The Round of 32 begins in the 2010 National Heads-Up Championship as the Clubs and Spades brackets take center stage. At the feature table, two icons face off as Phil Ivey takes on Scotty Nguyen in a marquee matchup. On the outer tables, Joe Hachem meets Gabe Kaplan, Jason Mercier battles Pieter de Korver, and Phil Gordon takes on Phil Laak. Also in action: Chris Moneymaker vs. Leo Wolpert, David Williams vs. Erik Seidel, Erick Lindgren vs. Peter Eastgate, and Stephen Quinn vs. Jamie Gold — all chasing the $500,000 top prize.
| Name | Type | Role | |
|---|---|---|---|
| Oliver 'Ali' Nejad | Host | Himself - Commentator | |
| Craig Hummer | Host | Himself - Commentator | |
| Leeann Tweeden | Host | Herself - Commentator |