Eric Adjepong brings seasoned competitors Tiffani Faison, Martel Stone and Shirley Chung to his underground late-night card game, and these competition-savvy chefs have $5,000 of their own hard-earned money for a night of culinary poker, smack talk and a head-to-head dessert challenge. In the end, someone's going to leave with a big stack of their friends' cash.