Eight chefs return from the previous seasons to compete against each other for $20,000 for their team's selected charity, and Season Three's contestants are introduced.QuickFire Challenge: Cook Perfect Eggs with One Hand behind Your Back Elimination Challenge: Create a Four Course Meal Using Scallops, Lobster, Duck & Kobe Beef
| Name | Type | Role | |
|---|---|---|---|
| Stephen Asprinio | Guest Star | ||
| Micah Edelstein | Guest Star | ||
| Camille Becerra | Guest Star | ||
| Sara Nguyen | Guest Star | ||
| Howie Kleinberg | Guest Star | ||
| Hung Hyunh | Guest Star | ||
| Tre Wilcox | Guest Star | ||
| Clay Bowen | Guest Star | ||
| Harold Dieterle | Guest Star | ||
| Brian Malarkey | Guest Star | ||
| Sandee Birdsong | Guest Star | ||
| Casey Thompson | Guest Star | ||
| Marcel Vigneron | Guest Star | ||
| Dave Martin | Guest Star | ||
| Joey Paulino | Guest Star | ||
| Dale Levitski | Guest Star | ||
| Sara Mair | Guest Star | ||
| Sam | Guest Star | ||
| C.J. Jacobson | Guest Star |