In this edition, the two Matthews head to Chianti country, the one-time home to a certain Mona Lisa Gherardini. Joe Fattorini visits the Maule valley to find out how hope can find roots in the vineyards at the epicentre of Chile's devastating 2010 earthquake. Chef Atul Kochhar fires up his tandoor to complement his favourite wine. Finally, the programme visits Moldova, a tiny country where a quarter of the population rely on wine for their livelihood, to find out just why Russia stopped buying their wine.