The Kitchen is getting spicy with Marcela Valladolid's classic Mexican Chili Rellenos, and chef and restauranteur Ming Tsai demonstrates fall-flavored Fried Wontons with Dipping Sauce. Then, learn how to prepare two comforting fall soups, and Jeff Mauro teaches actress Raven-Symone how to make Cavatelli and Vodka Sauce. Plus, holiday baking gadgets are tested and Geoffery Zakarian toasts to fall with a Vanilla-Scented Pear and Bourbon Spritz.