Jonathan Ross is joined by Hollywood star Vince Vaughn, best-selling grime and hip-hop musician Stormzy, award-winning actors Jamie Bell and Annette Bening, and presenter Bradley Walsh. Wasn't Expecting That singer Jamie Lawson performs live in the studio.
| Name | Type | Role | |
|---|---|---|---|
| Annette Bening | Guest Star | ||
| Bradley Walsh | Guest Star | ||
| Jamie Lawson | Guest Star | ||
| Stormzy | Guest Star | ||
| Vince Vaughn | Guest Star | ||
| Jamie Bell | Guest Star |