With the release of James Bond's Casino Royale in 2006, the world was not only introduced to a new era of Bond Films but also a new era of Bond Villains. Mads Mikkelsen as Le Chiffre was a very different turn for a long list of classic James Bond villains. Gone we're the over the top, mustache twirling bad guys, and in was a dark menacing villain with his back against the wall. Le Chiffre is hands down the most terrifying Bond Villain of all time.