The Round of 32 begins in the 2013 National Heads-Up Championship, with the Clubs and Spades brackets battling for spots in the Sweet 16 and a path to the $750,000 title. At the feature table, Antonio Esfandiari faces off against 2010 world champion Jonathan Duhamel. On the outer tables, Chris Moorman takes on Dan Cates, Kyle Julius meets Scott Seiver, and Vanessa Rousso squares off with Shaun Deeb. Also in action: Phil Ivey vs. Justin Bonomo, Mike Matusow vs. Viktor Blom, John Hennigan vs. Sam Simon, and Barry Greenstein vs. John Monnette.
| Name | Type | Role | |
|---|---|---|---|
| Matt Vasgersian | Host | Himself - Commentator | |
| Oliver 'Ali' Nejad | Host | Himself - Commentator | |
| Julie Donaldson | Host | Herself - Commentator |