Jools is joined by former Jane's Addiction singer Perry Farrell, with new band Porno for Pyros, making their British TV debut, Saint Etienne, Midnight Oil from Australia and soul singer Oleta Adams.
| Name | Type | Role | |
|---|---|---|---|
| Grant Lee Buffalo | Musical Guest | ||
| Midnight Oil | Musical Guest | ||
| Perry Farrell | Musical Guest | ||
| Porno for Pyros | Musical Guest | ||
| Oleta Adams | Musical Guest | ||
| Saint Etienne | Musical Guest |