Anxious to start a new life and stop living in her ex-husband's shadow, Andrea Kelly, ex-wife of R. Kelly, leaves her home town of Chicago to check out L.A. In L.A., she has a close friend in Nicole Murphy, ex-wife of Eddie Murphy. Nicole takes her under her wing and introduces Andrea to her friends and fellow Hollywood exes, Sheree Fletcher, ex-wife of Will Smith, Jessica Canseco, ex-wife of Jose Canseco, and Mayte Garcia, ex-wife of Prince. The women bond over their unique position as famous exes. Meanwhile, Jessica has lunch with Jose, who has a startling proposal for her.
Despite warnings from her friends, Jessica seriously considers letting Jose move back in with her. Anxious to meet Mr. Right, Mayte resorts to a professional matchmaker, who urges her to "de-Prince" her home. Meanwhile, Andrea finds a house and throws a wild housewarming party, during which Jessica shocks the others with tales from her lurid past.
Just when Jessica thinks she might still be in love with Jose, she receives a bombshell from him, and worries about how the news will affect their daughter, Josie. Andrea, now a small fish in a big pond, is overwhelmed by the stress of starting a master dance class in L.A. Meanwhile, Sheree and Terrell find themselves at odds over their long-distance marriage; at some point soon someone is going to have to move.
Anxious to escape the stress in their lives, the ladies head to Napa Valley for a weekend of fine food, fine wine, and (hopefully) fine men. During the trip, Jessica confronts Jose about his bad choices, and gives him an ultimatum.
Nicole sets Mayte up on her first blind date, which stresses Mayte out. Meanwhile, Jessica breaks the news about Jose to Josie, then is shocked to learn that Josie is planning a visit to Planned Parenthood.
Tony sets Andrea up on a date with a local friend. Andrea is willing to meet him, but worries how he will react when he finds out that R. Kelly is her ex. Meanwhile, Mayte plans a big party for her mother's birthday, and enlists the ladies to perform a scantily-clad belly dance for the crowd..
A weekend vacation in Palm Springs, Cal., turns tense and testy when Jessica lets an accusation fly. Sheree gives her some quick comeuppance by exposing a delicate subject.
Resentment lingers in Los Angeles in the wake of a showdown in Palm Springs, Cal. Particularly sensitive is Mayte, who receives distressing news and faces off against Jessica during a night out.
Nicole and Sheree speak to Mayte and Jessica respectively about the blow-up that occurred nights before. Andrea makes a decision about the future of her romance. Jessica invites all the ladies, including Mayte, to a polo event.
Sheree struggles to find support for her skin care product. Andrea schemes to come up with a way to better promote her under-attended dance classes. Nicole becomes flustered when nothing goes according to plan at her clothing line launch party.
In this dramatic season finale, Mayte and Andrea make physical attempts to put their exes behind them, once and for all. Later, during the run through of Andrea's upcoming dance benefit, one of the ladies has a serious and painful accident
ll is not well in the sisterhood of the HOLLYWOOD EXES. Drea, who has been spending more time back in Chicago, is offended by a comment Jessica recently tweeted, and plans to confront her.
Nicole's father suddenly passes away, prompting her to go to Sacramento and help her family make the funeral arrangements. Meanwhile, Jessica expresses her concerns to Mayte about her plans to adopt a baby. Mayte turns to Drea, who becomes increasingly annoyed with Jessica and plans to confront her during an upcoming private shopping party.
Nicole anticipates receiving an award during a glamorous charity event. At the event, she calms her nerves by drinking. A lot. By the time she gets to the stage, it becomes obvious that she's drunk.
Nicole receives a visit from her friend Shamicka Lawrence, the recent ex-wife of Martin Lawrence, and wants to introduce her to the other Hollywood Ex...
Shamicka meets up with Jessica, Sheree and Nicole in NYC, where Nicole will be making an appearance with her fiancé, Michael Strahan, on "Live with Kelly & Michael"
Jessica invites everyone to her lingerie-themed birthday party. Drea, who still has issues with Jessica, chooses not to attend. This prompts Jessica to confront her in person, during which all hell breaks loose....
Drea reveals the personal struggles she's dealing with back in Chicago, which play a part in her behavior towards Jessica. Nicole plans a birthday party and expects both Drea and Jessica to attend.
The girls head out of town for a weekend in [Park City. Mayte realizes the other women plan on wearing real fur. Shamicka, who is hosting the trip, is offended by Mayte's behavior. Things go from bad to worse when Mayte threatens to leave.
When Mayte and Jessica find Nicole's fur, they decide to make a statement by cooking it. When Nicole discovers what they've done, all hell breaks loose....
Nicole starts to think seriously about planning a wedding, and searches for the perfect dress while Jessica finds out that Jose has moved away, yet again....
With her foot still not fully healed, Drea produces a fitness video for curvy women. Meanwhile, Jessica and Mayte attend a Hollywood party where they run into Jessica's most recent ex, Garth, who is with his new girlfriend. Hoping to reconnect.
With coaxing from Mayte, Jessica decides to talk to Garth and find out if he still has feelings for her. While Mayte is recovering from surgery, Jessica gets her answer. Later, Drea wants to celebrate her birthday by teaching the others how to.
The girls head to Vegas to throw a bachelorette party for Nicole. Before they leave, Jessica finds out that Sheree told Shamicka about her "hood rat" comment, and feels betrayed. Similarly, Shamicka plans to confront Jessica once they all get to Vegas. Things take an unexpected turn, however, when Mayte compares pole dancing to posing nude for Playboy, which Jessica did several years ago. As the night progresses, things go from bad to worse, and Nicole's bachelorette party might be ruined.
A new girl joins the team as the the women gather at Nicole’s house for brunch. Drea receives an unexpected surprise.
Drea brings the women together for dinner in hopes that Mayte and Nicole can bury the hatchet. Unfortunately, a stubborn Mayte digs in her heels.
At Drea’s birthday party, the women grill her about getting a pre-nup, causing Drea to meltdown and Brian to explode.
In the wake of Shanna’s bombshell, the women decide to sit Jessica down and give her a chance to explain. Meanwhile, Mayte is concerned about her ability to have more children and Drea comes to a heartbreaking realization.
Drea and Shamicka refuse to go on a trip that Nicole has organized to Hawaii, when they believe Jessica is also invited. Shanna reaches out to a therapist to try and beat her fear of flying.
Aloha! The ladies are in Hawaii for fun, sun and sisterhood. But while Drea, Shamicka and Shanna are thrilled to be without Jessica – her absence isn’t sitting right with Nicole.
The week of Drea’s wedding has arrived and a sudden appearance by Jessica has everyone reeling